Table 1.

Interaction of thiophenols with perfluoroalkyl iodides in liquid ammonia under UV irradiation.

R	RF	Yields of ArSRF, %	Ref.
H	CF3	76	[143]
	C2F5, n-C3F7, iso-C3F7	84, 81, 76	[144]
4-NH2	CF3	87	[146]
2-NH2	CF3	71	[143]
4-OH	CF3	69.5	[143]
2-OCH3	CF3	86	[98]
4-Cl	CF3	72	[146]
	C2F5, n-C3F7, iso-C3F7	84, 83, 65	[144]
2-SO2CHF2	CF3	69	[143,146]
4-SO2CF3	CF3	78	[143,146]
4-NO2	CF3	2.7a	[143,146]
		63b	[143,146]
2,4-Cl2	CF3	87	[149]
	C3F7	89	[149]
2-COOH	CF3	90	[150]
3- and 4-COOCH3	CF3, n-C3F7, iso-C3F7	70–80	[151]
3- and 4-F	CF3, n-C3F7	80–90	[152]
	iso-C3F7	72–75	[152]
4-NHCOCH3	CF3	96	[153]
4-NHCOOCH3	CF3, n-C3F7	88 (92c), 82 (93c)	[9]
	C2F5, C4F9	62, 55	[154]

^aIn a quartz flask.

^bIn a quartz ampoule at 30–45 °C.

^cWith preliminary reduction of 4,4′-bis(MeOCONH)diaryl disulfide and without the isolation of corresponding thiophenol.