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. 2010 Aug 18;6:880–921. doi: 10.3762/bjoc.6.88

Table 10.

Catalysis of trifluoromethylation by methylviologen [186].

graphic file with name Beilstein_J_Org_Chem-06-880-i007.jpg

R MV2+, % Yields of ArSCF3,%

With MV2+ Without MV2+

H 6.5 91.2 3
Cl 7.0 100.0 5
NO2 7.9 9.2
NHCOOMe 6.9 88.5 11