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. 2010 Aug 18;6:880–921. doi: 10.3762/bjoc.6.88

Table 15.

Reaction of the CF3− anion derived from fluoroform with S-derivatives of thiophenols.

graphic file with name Beilstein_J_Org_Chem-06-880-i011.jpg
B R X Yield, % Ref.
t-BuOK H SPh 80 [243]
t-BuOK H SO2Ph 90 [243]
t-BuOK 4-NO2 Cl 60 [243]
LiN(TMS)2/NH(TMS)2 H SPh 4 [244]
N(TMS)3/Me4NF H SPh 6 [244]
t-BuOK H SPh 82 [244]
N(TMS)3/Me4NF H SePh 61a [244]
t-BuOK H SePh 77a [244]

aPhSeCF3.