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. Author manuscript; available in PMC: 2011 Sep 20.
Published in final edited form as: Inorg Chem. 2010 Sep 20;49(18):8310–8322. doi: 10.1021/ic100870v

Figure 6.

Figure 6

Mössbauer spectrum (A) of 1-F recorded at 100 K in a parallel field of 50 mT. The red line in (A) indicates the contribution of a 22% diferric contaminant (same as in Figure 4A). Subtraction of this contaminant yields the spectrum (hashed) of 1-F, shown in (B). The solid line in (B) is the superposition of a doublet representing the FeIII site (doublet a) with a doublet (b) belonging to the FeIV site of 1-F. The broad wings indicate that the electronic system has not yet attained the fast fluctuation limit.