| C1—N1 | 1.316 (3) | C6—N2 | 1.425 (3) |
| C1—N2 | 1.331 (3) | C7—N4 | 1.326 (3) |
| C1—H1 | 0.9300 | C7—C8 | 1.372 (5) |
| C2—C8 | 1.361 (5) | C7—Cl1 | 1.729 (3) |
| C2—C5 | 1.387 (4) | C8—H8 | 0.9300 |
| C2—H2 | 0.9300 | Cd1—N5i | 2.319 (2) |
| C3—N3 | 1.303 (3) | Cd1—N5 | 2.319 (2) |
| C3—N1 | 1.356 (3) | Cd1—N1 | 2.328 (2) |
| C3—H3 | 0.9300 | Cd1—N1i | 2.328 (2) |
| C4—N5 | 1.146 (4) | Cd1—S1ii | 2.7696 (9) |
| C4—S1 | 1.646 (3) | Cd1—S1iii | 2.7696 (9) |
| C5—C6 | 1.371 (4) | N2—N3 | 1.360 (3) |
| C5—H5 | 0.9300 | S1—Cd1iv | 2.7696 (9) |
| C6—N4 | 1.319 (4) | ||
| N1—C1—N2 | 109.8 (2) | N5—Cd1—N1 | 90.49 (9) |
| N1—C1—H1 | 125.1 | N5i—Cd1—N1i | 90.49 (9) |
| N2—C1—H1 | 125.1 | N5—Cd1—N1i | 89.51 (9) |
| C8—C2—C5 | 120.1 (3) | N1—Cd1—N1i | 180.000 (1) |
| C8—C2—H2 | 120.0 | N5i—Cd1—S1ii | 91.29 (7) |
| C5—C2—H2 | 120.0 | N5—Cd1—S1ii | 88.71 (7) |
| N3—C3—N1 | 115.0 (3) | N1—Cd1—S1ii | 90.02 (6) |
| N3—C3—H3 | 122.5 | N1i—Cd1—S1ii | 89.98 (6) |
| N1—C3—H3 | 122.5 | N5i—Cd1—S1iii | 88.71 (7) |
| N5—C4—S1 | 179.1 (3) | N5—Cd1—S1iii | 91.29 (7) |
| C6—C5—C2 | 116.3 (3) | N1—Cd1—S1iii | 89.98 (6) |
| C6—C5—H5 | 121.9 | N1i—Cd1—S1iii | 90.02 (6) |
| C2—C5—H5 | 121.9 | S1ii—Cd1—S1iii | 180.0 |
| N4—C6—C5 | 125.8 (3) | C1—N1—C3 | 103.0 (2) |
| N4—C6—N2 | 114.1 (2) | C1—N1—Cd1 | 127.88 (18) |
| C5—C6—N2 | 120.1 (3) | C3—N1—Cd1 | 129.05 (18) |
| N4—C7—C8 | 124.9 (3) | C1—N2—N3 | 110.0 (2) |
| N4—C7—Cl1 | 115.9 (2) | C1—N2—C6 | 129.0 (2) |
| C8—C7—Cl1 | 119.2 (2) | N3—N2—C6 | 120.9 (2) |
| C2—C8—C7 | 117.6 (3) | C3—N3—N2 | 102.2 (2) |
| C2—C8—H8 | 121.2 | C6—N4—C7 | 115.4 (2) |
| C7—C8—H8 | 121.2 | C4—N5—Cd1 | 145.7 (2) |
| N5i—Cd1—N5 | 180.0 | C4—S1—Cd1iv | 97.18 (11) |
| N5i—Cd1—N1 | 89.51 (9) | ||
| C8—C2—C5—C6 | 0.6 (5) | N1—C1—N2—N3 | 0.1 (3) |
| C2—C5—C6—N4 | −1.0 (5) | N1—C1—N2—C6 | 177.3 (3) |
| C2—C5—C6—N2 | 178.3 (3) | N4—C6—N2—C1 | −1.0 (4) |
| C5—C2—C8—C7 | 0.0 (5) | C5—C6—N2—C1 | 179.6 (3) |
| N4—C7—C8—C2 | −0.3 (5) | N4—C6—N2—N3 | 175.9 (2) |
| Cl1—C7—C8—C2 | −179.4 (3) | C5—C6—N2—N3 | −3.5 (4) |
| N2—C1—N1—C3 | −0.1 (3) | N1—C3—N3—N2 | −0.1 (4) |
| N2—C1—N1—Cd1 | −176.61 (18) | C1—N2—N3—C3 | 0.0 (3) |
| N3—C3—N1—C1 | 0.1 (4) | C6—N2—N3—C3 | −177.5 (3) |
| N3—C3—N1—Cd1 | 176.6 (2) | C5—C6—N4—C7 | 0.8 (4) |
| N5i—Cd1—N1—C1 | −1.9 (3) | N2—C6—N4—C7 | −178.6 (2) |
| N5—Cd1—N1—C1 | 178.1 (3) | C8—C7—N4—C6 | −0.1 (4) |
| S1ii—Cd1—N1—C1 | −93.2 (2) | Cl1—C7—N4—C6 | 179.1 (2) |
| S1iii—Cd1—N1—C1 | 86.8 (2) | N1—Cd1—N5—C4 | −14.4 (5) |
| N5i—Cd1—N1—C3 | −177.6 (3) | N1i—Cd1—N5—C4 | 165.6 (5) |
| N5—Cd1—N1—C3 | 2.4 (3) | S1ii—Cd1—N5—C4 | −104.4 (4) |
| S1ii—Cd1—N1—C3 | 91.1 (3) | S1iii—Cd1—N5—C4 | 75.6 (4) |
| S1iii—Cd1—N1—C3 | −88.9 (3) |