| Br1—C3 | 1.900 (4) | C9—C10 | 1.403 (5) |
| S1—O1 | 1.425 (3) | C9—H9 | 0.9300 |
| S1—O2 | 1.429 (3) | C10—C11 | 1.399 (5) |
| S1—O3 | 1.601 (3) | C10—C13 | 1.475 (5) |
| S1—C6 | 1.758 (4) | C11—C12 | 1.394 (5) |
| N1—C13 | 1.292 (4) | C11—H11 | 0.9300 |
| N1—C14 | 1.401 (4) | C12—H12 | 0.9300 |
| N2—C16 | 1.362 (4) | C13—H13 | 0.9300 |
| N2—N3 | 1.416 (4) | C14—C16 | 1.380 (5) |
| N2—C18 | 1.474 (4) | C14—C15 | 1.451 (5) |
| N3—C15 | 1.418 (4) | C16—C17 | 1.497 (5) |
| N3—C19 | 1.433 (5) | C17—H17A | 0.9600 |
| O3—C7 | 1.430 (4) | C17—H17B | 0.9600 |
| O4—C15 | 1.239 (4) | C17—H17C | 0.9600 |
| C1—C2 | 1.380 (5) | C18—H18A | 0.9600 |
| C1—C6 | 1.398 (5) | C18—H18B | 0.9600 |
| C1—H1 | 0.9300 | C18—H18C | 0.9600 |
| C2—C3 | 1.381 (5) | C19—C24 | 1.386 (5) |
| C2—H2 | 0.9300 | C19—C20 | 1.394 (5) |
| C3—C4 | 1.390 (5) | C20—C21 | 1.387 (6) |
| C4—C5 | 1.382 (6) | C20—H20 | 0.9300 |
| C4—H4 | 0.9300 | C21—C22 | 1.378 (6) |
| C5—C6 | 1.393 (5) | C21—H21 | 0.9300 |
| C5—H5 | 0.9300 | C22—C23 | 1.380 (6) |
| C7—C12 | 1.370 (5) | C22—H22 | 0.9300 |
| C7—C8 | 1.378 (5) | C23—C24 | 1.380 (6) |
| C8—C9 | 1.385 (5) | C23—H23 | 0.9300 |
| C8—H8 | 0.9300 | C24—H24 | 0.9300 |
| O1—S1—O2 | 121.36 (18) | C10—C11—H11 | 119.5 |
| O1—S1—O3 | 103.89 (16) | C7—C12—C11 | 118.5 (4) |
| O2—S1—O3 | 109.24 (15) | C7—C12—H12 | 120.7 |
| O1—S1—C6 | 108.71 (18) | C11—C12—H12 | 120.7 |
| O2—S1—C6 | 109.24 (17) | N1—C13—C10 | 121.7 (3) |
| O3—S1—C6 | 102.77 (16) | N1—C13—H13 | 119.2 |
| C13—N1—C14 | 120.5 (3) | C10—C13—H13 | 119.2 |
| C16—N2—N3 | 107.3 (3) | C16—C14—N1 | 123.0 (3) |
| C16—N2—C18 | 124.8 (3) | C16—C14—C15 | 107.8 (3) |
| N3—N2—C18 | 118.4 (3) | N1—C14—C15 | 129.2 (3) |
| N2—N3—C15 | 108.9 (3) | O4—C15—N3 | 123.2 (3) |
| N2—N3—C19 | 119.4 (3) | O4—C15—C14 | 131.9 (3) |
| C15—N3—C19 | 123.9 (3) | N3—C15—C14 | 104.9 (3) |
| C7—O3—S1 | 119.9 (2) | N2—C16—C14 | 110.5 (3) |
| C2—C1—C6 | 120.1 (4) | N2—C16—C17 | 121.9 (3) |
| C2—C1—H1 | 120.0 | C14—C16—C17 | 127.5 (4) |
| C6—C1—H1 | 120.0 | C16—C17—H17A | 109.5 |
| C1—C2—C3 | 120.4 (4) | C16—C17—H17B | 109.5 |
| C1—C2—H2 | 119.8 | H17A—C17—H17B | 109.5 |
| C3—C2—H2 | 119.8 | C16—C17—H17C | 109.5 |
| C2—C3—C4 | 120.0 (4) | H17A—C17—H17C | 109.5 |
| C2—C3—Br1 | 120.8 (3) | H17B—C17—H17C | 109.5 |
| C4—C3—Br1 | 119.1 (3) | N2—C18—H18A | 109.5 |
| C5—C4—C3 | 119.9 (4) | N2—C18—H18B | 109.5 |
| C5—C4—H4 | 120.0 | H18A—C18—H18B | 109.5 |
| C3—C4—H4 | 120.0 | N2—C18—H18C | 109.5 |
| C4—C5—C6 | 120.3 (4) | H18A—C18—H18C | 109.5 |
| C4—C5—H5 | 119.8 | H18B—C18—H18C | 109.5 |
| C6—C5—H5 | 119.8 | C24—C19—C20 | 120.2 (4) |
| C5—C6—C1 | 119.2 (4) | C24—C19—N3 | 121.5 (3) |
| C5—C6—S1 | 119.0 (3) | C20—C19—N3 | 118.2 (3) |
| C1—C6—S1 | 121.7 (3) | C21—C20—C19 | 119.1 (4) |
| C12—C7—C8 | 122.2 (4) | C21—C20—H20 | 120.5 |
| C12—C7—O3 | 118.7 (3) | C19—C20—H20 | 120.5 |
| C8—C7—O3 | 118.9 (4) | C22—C21—C20 | 120.9 (4) |
| C7—C8—C9 | 119.3 (4) | C22—C21—H21 | 119.5 |
| C7—C8—H8 | 120.3 | C20—C21—H21 | 119.5 |
| C9—C8—H8 | 120.3 | C21—C22—C23 | 119.3 (4) |
| C8—C9—C10 | 120.5 (4) | C21—C22—H22 | 120.4 |
| C8—C9—H9 | 119.8 | C23—C22—H22 | 120.4 |
| C10—C9—H9 | 119.8 | C24—C23—C22 | 121.1 (4) |
| C11—C10—C9 | 118.5 (4) | C24—C23—H23 | 119.5 |
| C11—C10—C13 | 119.5 (3) | C22—C23—H23 | 119.5 |
| C9—C10—C13 | 122.0 (3) | C23—C24—C19 | 119.4 (4) |
| C12—C11—C10 | 121.0 (4) | C23—C24—H24 | 120.3 |
| C12—C11—H11 | 119.5 | C19—C24—H24 | 120.3 |
| C16—N2—N3—C15 | −7.1 (4) | C10—C11—C12—C7 | −0.1 (6) |
| C18—N2—N3—C15 | −155.2 (3) | C14—N1—C13—C10 | −177.2 (3) |
| C16—N2—N3—C19 | −157.5 (3) | C11—C10—C13—N1 | −171.6 (3) |
| C18—N2—N3—C19 | 54.4 (4) | C9—C10—C13—N1 | 11.5 (6) |
| O1—S1—O3—C7 | −152.2 (3) | C13—N1—C14—C16 | −175.3 (3) |
| O2—S1—O3—C7 | −21.4 (3) | C13—N1—C14—C15 | 5.1 (6) |
| C6—S1—O3—C7 | 94.5 (3) | N2—N3—C15—O4 | −174.2 (3) |
| C6—C1—C2—C3 | −0.4 (6) | C19—N3—C15—O4 | −25.4 (5) |
| C1—C2—C3—C4 | −1.3 (6) | N2—N3—C15—C14 | 4.5 (4) |
| C1—C2—C3—Br1 | 176.6 (3) | C19—N3—C15—C14 | 153.3 (3) |
| C2—C3—C4—C5 | 1.8 (6) | C16—C14—C15—O4 | 178.2 (4) |
| Br1—C3—C4—C5 | −176.2 (3) | N1—C14—C15—O4 | −2.2 (6) |
| C3—C4—C5—C6 | −0.6 (7) | C16—C14—C15—N3 | −0.4 (4) |
| C4—C5—C6—C1 | −1.1 (6) | N1—C14—C15—N3 | 179.2 (3) |
| C4—C5—C6—S1 | 177.1 (3) | N3—N2—C16—C14 | 6.9 (4) |
| C2—C1—C6—C5 | 1.6 (6) | C18—N2—C16—C14 | 152.4 (3) |
| C2—C1—C6—S1 | −176.6 (3) | N3—N2—C16—C17 | −172.9 (3) |
| O1—S1—C6—C5 | −19.4 (4) | C18—N2—C16—C17 | −27.4 (5) |
| O2—S1—C6—C5 | −153.8 (3) | N1—C14—C16—N2 | 176.3 (3) |
| O3—S1—C6—C5 | 90.3 (3) | C15—C14—C16—N2 | −4.0 (4) |
| O1—S1—C6—C1 | 158.8 (3) | N1—C14—C16—C17 | −3.9 (6) |
| O2—S1—C6—C1 | 24.4 (4) | C15—C14—C16—C17 | 175.7 (3) |
| O3—S1—C6—C1 | −91.5 (3) | N2—N3—C19—C24 | 29.2 (5) |
| S1—O3—C7—C12 | 86.2 (4) | C15—N3—C19—C24 | −116.5 (4) |
| S1—O3—C7—C8 | −99.0 (4) | N2—N3—C19—C20 | −152.1 (3) |
| C12—C7—C8—C9 | −0.1 (6) | C15—N3—C19—C20 | 62.2 (5) |
| O3—C7—C8—C9 | −174.7 (3) | C24—C19—C20—C21 | 1.0 (5) |
| C7—C8—C9—C10 | 0.0 (6) | N3—C19—C20—C21 | −177.7 (3) |
| C8—C9—C10—C11 | 0.0 (5) | C19—C20—C21—C22 | −1.7 (6) |
| C8—C9—C10—C13 | 176.9 (3) | C20—C21—C22—C23 | 1.2 (7) |
| C9—C10—C11—C12 | 0.1 (6) | C21—C22—C23—C24 | 0.1 (7) |
| C13—C10—C11—C12 | −177.0 (4) | C22—C23—C24—C19 | −0.8 (7) |
| C8—C7—C12—C11 | 0.1 (6) | C20—C19—C24—C23 | 0.3 (6) |
| O3—C7—C12—C11 | 174.8 (3) | N3—C19—C24—C23 | 178.9 (4) |