Cu1—O1 | 1.920 (3) | C8—C9 | 1.361 (6) |
Cu1—O1i | 1.920 (3) | C8—H8 | 0.9300 |
Cu1—N2 | 1.946 (3) | C9—C10 | 1.409 (7) |
Cu1—N2i | 1.946 (3) | C9—H9 | 0.9300 |
Cu2—N1 | 1.884 (3) | C10—C11 | 1.360 (7) |
Cu2—O2 | 1.890 (3) | C10—H10 | 0.9300 |
Cu2—O3 | 1.953 (3) | C11—H11 | 0.9300 |
Cu2—N3 | 1.975 (3) | C12—C13 | 1.516 (6) |
N1—C1 | 1.323 (5) | C13—C15 | 1.518 (8) |
N1—N2 | 1.412 (5) | C13—C14 | 1.529 (8) |
N2—C12 | 1.320 (5) | C13—H13 | 0.9800 |
N3—C20 | 1.326 (5) | C14—H14A | 0.9600 |
N3—C16 | 1.354 (5) | C14—H14B | 0.9600 |
O1—C1 | 1.294 (5) | C14—H14C | 0.9600 |
O2—C2 | 1.315 (5) | C15—H15A | 0.9600 |
O3—C12 | 1.285 (5) | C15—H15B | 0.9600 |
C1—C3 | 1.465 (5) | C15—H15C | 0.9600 |
C2—C3 | 1.405 (5) | C16—C17 | 1.365 (6) |
C2—C7 | 1.455 (6) | C16—H16 | 0.9300 |
C3—C4 | 1.425 (6) | C17—C18 | 1.367 (7) |
C4—C5 | 1.342 (6) | C17—H17 | 0.9300 |
C4—H4 | 0.9300 | C18—C19 | 1.384 (7) |
C5—C6 | 1.423 (6) | C18—H18 | 0.9300 |
C5—H5 | 0.9300 | C19—C20 | 1.374 (6) |
C6—C11 | 1.412 (6) | C19—H19 | 0.9300 |
C6—C7 | 1.433 (6) | C20—H20 | 0.9300 |
C7—C8 | 1.406 (6) | ||
O1—Cu1—O1i | 159.21 (19) | C7—C8—H8 | 119.5 |
O1—Cu1—N2 | 82.65 (13) | C8—C9—C10 | 121.0 (5) |
O1i—Cu1—N2 | 100.87 (13) | C8—C9—H9 | 119.5 |
O1—Cu1—N2i | 100.87 (13) | C10—C9—H9 | 119.5 |
O1i—Cu1—N2i | 82.65 (13) | C11—C10—C9 | 119.2 (4) |
N2—Cu1—N2i | 160.7 (2) | C11—C10—H10 | 120.4 |
N1—Cu2—O2 | 93.11 (13) | C9—C10—H10 | 120.4 |
N1—Cu2—O3 | 81.17 (13) | C10—C11—C6 | 122.0 (5) |
O2—Cu2—O3 | 173.00 (13) | C10—C11—H11 | 119.0 |
N1—Cu2—N3 | 172.94 (14) | C6—C11—H11 | 119.0 |
O2—Cu2—N3 | 92.88 (13) | O3—C12—N2 | 122.2 (4) |
O3—Cu2—N3 | 93.10 (13) | O3—C12—C13 | 117.8 (4) |
C1—N1—N2 | 114.0 (3) | N2—C12—C13 | 120.0 (4) |
C1—N1—Cu2 | 130.2 (3) | C12—C13—C15 | 109.9 (4) |
N2—N1—Cu2 | 115.1 (3) | C12—C13—C14 | 110.1 (4) |
C12—N2—N1 | 109.9 (3) | C15—C13—C14 | 111.2 (5) |
C12—N2—Cu1 | 139.2 (3) | C12—C13—H13 | 108.5 |
N1—N2—Cu1 | 110.4 (2) | C15—C13—H13 | 108.5 |
C20—N3—C16 | 117.3 (4) | C14—C13—H13 | 108.5 |
C20—N3—Cu2 | 122.2 (3) | C13—C14—H14A | 109.5 |
C16—N3—Cu2 | 120.4 (3) | C13—C14—H14B | 109.5 |
C1—O1—Cu1 | 112.8 (3) | H14A—C14—H14B | 109.5 |
C2—O2—Cu2 | 126.6 (3) | C13—C14—H14C | 109.5 |
C12—O3—Cu2 | 111.4 (3) | H14A—C14—H14C | 109.5 |
O1—C1—N1 | 120.1 (4) | H14B—C14—H14C | 109.5 |
O1—C1—C3 | 119.8 (4) | C13—C15—H15A | 109.5 |
N1—C1—C3 | 120.1 (3) | C13—C15—H15B | 109.5 |
O2—C2—C3 | 125.9 (4) | H15A—C15—H15B | 109.5 |
O2—C2—C7 | 116.0 (4) | C13—C15—H15C | 109.5 |
C3—C2—C7 | 118.1 (4) | H15A—C15—H15C | 109.5 |
C2—C3—C4 | 119.4 (4) | H15B—C15—H15C | 109.5 |
C2—C3—C1 | 123.3 (4) | N3—C16—C17 | 123.1 (4) |
C4—C3—C1 | 117.3 (3) | N3—C16—H16 | 118.5 |
C5—C4—C3 | 123.1 (4) | C17—C16—H16 | 118.5 |
C5—C4—H4 | 118.5 | C16—C17—C18 | 118.6 (4) |
C3—C4—H4 | 118.5 | C16—C17—H17 | 120.7 |
C4—C5—C6 | 120.6 (4) | C18—C17—H17 | 120.7 |
C4—C5—H5 | 119.7 | C17—C18—C19 | 119.4 (4) |
C6—C5—H5 | 119.7 | C17—C18—H18 | 120.3 |
C11—C6—C5 | 123.4 (4) | C19—C18—H18 | 120.3 |
C11—C6—C7 | 118.2 (4) | C20—C19—C18 | 118.4 (5) |
C5—C6—C7 | 118.4 (4) | C20—C19—H19 | 120.8 |
C8—C7—C6 | 118.6 (4) | C18—C19—H19 | 120.8 |
C8—C7—C2 | 120.9 (4) | N3—C20—C19 | 123.2 (4) |
C6—C7—C2 | 120.5 (4) | N3—C20—H20 | 118.4 |
C9—C8—C7 | 121.0 (5) | C19—C20—H20 | 118.4 |
C9—C8—H8 | 119.5 | ||
O2—Cu2—N1—C1 | −10.5 (4) | N1—C1—C3—C4 | 174.6 (4) |
O3—Cu2—N1—C1 | 173.6 (4) | C2—C3—C4—C5 | 0.4 (6) |
O2—Cu2—N1—N2 | 179.6 (3) | C1—C3—C4—C5 | −177.8 (4) |
O3—Cu2—N1—N2 | 3.6 (3) | C3—C4—C5—C6 | −0.9 (7) |
C1—N1—N2—C12 | −174.6 (4) | C4—C5—C6—C11 | 179.9 (4) |
Cu2—N1—N2—C12 | −3.0 (5) | C4—C5—C6—C7 | −0.1 (6) |
C1—N1—N2—Cu1 | −0.9 (5) | C11—C6—C7—C8 | −0.1 (6) |
Cu2—N1—N2—Cu1 | 170.69 (17) | C5—C6—C7—C8 | 179.8 (4) |
O1—Cu1—N2—C12 | 172.5 (5) | C11—C6—C7—C2 | −178.4 (4) |
O1i—Cu1—N2—C12 | −28.3 (5) | C5—C6—C7—C2 | 1.6 (6) |
N2i—Cu1—N2—C12 | 70.6 (5) | O2—C2—C7—C8 | −1.0 (6) |
O1—Cu1—N2—N1 | 1.6 (3) | C3—C2—C7—C8 | 179.8 (4) |
O1i—Cu1—N2—N1 | 160.8 (3) | O2—C2—C7—C6 | 177.1 (4) |
N2i—Cu1—N2—N1 | −100.4 (3) | C3—C2—C7—C6 | −2.1 (6) |
O2—Cu2—N3—C20 | −23.5 (4) | C6—C7—C8—C9 | −0.4 (7) |
O3—Cu2—N3—C20 | 152.8 (4) | C2—C7—C8—C9 | 177.8 (5) |
O2—Cu2—N3—C16 | 154.6 (3) | C7—C8—C9—C10 | 0.7 (8) |
O3—Cu2—N3—C16 | −29.1 (3) | C8—C9—C10—C11 | −0.3 (9) |
O1i—Cu1—O1—C1 | −103.3 (3) | C9—C10—C11—C6 | −0.3 (8) |
N2—Cu1—O1—C1 | −2.0 (3) | C5—C6—C11—C10 | −179.4 (5) |
N2i—Cu1—O1—C1 | 158.7 (3) | C7—C6—C11—C10 | 0.5 (7) |
N1—Cu2—O2—C2 | 6.4 (3) | Cu2—O3—C12—N2 | 3.1 (6) |
N3—Cu2—O2—C2 | −169.9 (3) | Cu2—O3—C12—C13 | −178.6 (3) |
N1—Cu2—O3—C12 | −3.6 (3) | N1—N2—C12—O3 | −0.2 (6) |
N3—Cu2—O3—C12 | 172.2 (3) | Cu1—N2—C12—O3 | −171.2 (3) |
Cu1—O1—C1—N1 | 2.2 (5) | N1—N2—C12—C13 | −178.4 (4) |
Cu1—O1—C1—C3 | −179.0 (3) | Cu1—N2—C12—C13 | 10.7 (8) |
N2—N1—C1—O1 | −0.8 (6) | O3—C12—C13—C15 | −69.6 (6) |
Cu2—N1—C1—O1 | −170.8 (3) | N2—C12—C13—C15 | 108.6 (5) |
N2—N1—C1—C3 | −179.6 (3) | O3—C12—C13—C14 | 53.2 (6) |
Cu2—N1—C1—C3 | 10.4 (6) | N2—C12—C13—C14 | −128.5 (5) |
Cu2—O2—C2—C3 | −3.0 (6) | C20—N3—C16—C17 | 0.9 (6) |
Cu2—O2—C2—C7 | 177.9 (3) | Cu2—N3—C16—C17 | −177.3 (3) |
O2—C2—C3—C4 | −178.1 (4) | N3—C16—C17—C18 | −0.7 (7) |
C7—C2—C3—C4 | 1.1 (6) | C16—C17—C18—C19 | −0.5 (7) |
O2—C2—C3—C1 | 0.1 (7) | C17—C18—C19—C20 | 1.4 (8) |
C7—C2—C3—C1 | 179.2 (4) | C16—N3—C20—C19 | 0.0 (7) |
O1—C1—C3—C2 | 177.6 (4) | Cu2—N3—C20—C19 | 178.2 (4) |
N1—C1—C3—C2 | −3.6 (6) | C18—C19—C20—N3 | −1.2 (8) |
O1—C1—C3—C4 | −4.3 (6) |