Table 1.
Initial and final water concentrations for reactions in MTBE.
| “Dry” | Sat. | 0–2 | 2–7 | 7–12 | |
|---|---|---|---|---|---|
| water concentration of solvent [ppm] | 2400[a] | 13 100[b] | – | – | – |
| water concentration of solvent + salt pair [ppm] | – | – | 4000[c] | 5000[c] | 8200[c] |
| initial water concentration of the reaction mixture [ppm] | 7700[d] | 13 000[d] | 2000[e] | 3200[e] | 3600[e] |
| final water concentration of the reaction mixture [ppm][f] | 10 300 | 16 300 | 8200 | 9600 | 12 300 |
Measured for a sample of anhydrous solvent from Sigma–Aldrich.
Measured for a sample of water-saturated solvent.
In a separate experiment, the salt pairs were suspended in the anhydrous solvent and the system was stirred for 1 h before measuring the water concentration.
Measured after stirring the CLEA in the solvent for 1 h.
Measured after stirring the CLEA and the salt pair in the solvent for 1 h.
Measured for the reaction mixture after 24 h.