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. 2010 May 18;16(25):7596–7604. doi: 10.1002/chem.201000487

Table 1.

Initial and final water concentrations for reactions in MTBE.

“Dry” Sat. 0–2 2–7 7–12
water concentration of solvent [ppm] 2400[a] 13 100[b]
water concentration of solvent + salt pair [ppm] 4000[c] 5000[c] 8200[c]
initial water concentration of the reaction mixture [ppm] 7700[d] 13 000[d] 2000[e] 3200[e] 3600[e]
final water concentration of the reaction mixture [ppm][f] 10 300 16 300 8200 9600 12 300
[a]

Measured for a sample of anhydrous solvent from Sigma–Aldrich.

[b]

Measured for a sample of water-saturated solvent.

[c]

In a separate experiment, the salt pairs were suspended in the anhydrous solvent and the system was stirred for 1 h before measuring the water concentration.

[d]

Measured after stirring the CLEA in the solvent for 1 h.

[e]

Measured after stirring the CLEA and the salt pair in the solvent for 1 h.

[f]

Measured for the reaction mixture after 24 h.