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. 2010 May 18;16(25):7596–7604. doi: 10.1002/chem.201000487

Table 2.

Initial and final water concentrations for (S)-mandelonitrile (3) synthesis in MTBE in the presence and absence of Na2HPO42 H2O/Na2HPO47 H2O.

Salt kept during the reaction Salt removed (standard conditions) Control experiments
1 2
initial water concentration [ppm] 3500[a] 3200[a] 4200[c] 3100[d]
final water concentration [ppm] 32 000[b] 9600[b] 5500[c] 10 100[d]
[a]

Measured after stirring the CLEA in the solvent for 1 h in the presence of the salt pair “2–7”.

[b]

Measured for the reaction mixture after 24 h.

[c]

The CLEA was stirred in the solvent in the presence of the salt pair “2-7” but without reagents for 24 h. The water concentration was measured after 1 h and after 24 h.

[d]

The reagents were stirred in the solvent in the presence of the salt pair “2-7” but without the CLEA. The water concentration was measured after 1 h and after 24 h.