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. Author manuscript; available in PMC: 2011 Nov 3.
Published in final edited form as: J Am Chem Soc. 2010 Nov 3;132(43):15116–15119. doi: 10.1021/ja105829t

Table 1.

Identification of a Ligand for Palladium-Catalyzed Aerobic Allylic Acetoxylation.a

graphic file with name nihms244136u2.jpg
Entry Ligand Yieldb Entry Ligand Yieldb
1 None 4% 7 graphic file with name nihms244136t1.jpg 0%
2 graphic file with name nihms244136t2.jpgc 4% 8 graphic file with name nihms244136t3.jpg 9%
3 graphic file with name nihms244136t4.jpg 4% 9 graphic file with name nihms244136t5.jpg 0%
4 graphic file with name nihms244136t6.jpg 0% 10 graphic file with name nihms244136t7.jpg 0%
5 graphic file with name nihms244136t8.jpg 0% 11 graphic file with name nihms244136t9.jpg 4%
6 graphic file with name nihms244136t10.jpg 3% 12 graphic file with name nihms244136t11.jpg 81%
a

5% Pd(OAc)2 (3 mg, 0.0134 mmol), 5% ligand (0.0134 mmol), allyl benzene (35 μL, 0.268 mmol), AcOH (1 mL), 1 atm O2, 80 °C, 18h.

b

GC (internal std = nitrobenzene).

c

10%