Table 2. Methyl signal line-width,ν1/2, (Hz) in different solutions of decamera.
Sample |
Monovalent cation
(mM) |
[K+]
(mM) |
pH | ν1/2 | ||
|
T5 |
T4 |
T7 |
|||
1 | 152 | 114 | 7.0 | 6.5 | 5.6 | 5.9 |
2 | 152b | 114 | 7.0 | 7.8 | 4.3 | 6.3 |
190c | 114 | 7.0 | 6.7 | 3.8 | 5.3 | |
3 | 152 | 114 | 7.0 | 4.9 | 4.3 | 4.5 |
4 | 118 | 0 | 6.0 | 15.0 | 9.0 | 11.1 |
5 | 228 | 114 | 6.0 | 7.0 | 4.2 | 5.2 |
6 | 152 | 0 | 6.0 | 21.1 | 17.0 | 19.7 |
7 | 190d | 38 | 6.0 | 13.0 | 10.5 | 12.0 |
aThe line-width of TSP signal is in the range of 0.8–1.2 Hz for all studied samples. Phosphate ion concentration is 38 mM in all samples except 5, which is 76 mM in phosphate ion. Samples 1–3 are in D2O and 4–7 in H2O/D2O, 9:1 v/v.
bOriginal sample 2.
cSample 2 with 38 mM of NaCl added.
dSample 6 with 38 mM of KCl added.