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. Author manuscript; available in PMC: 2011 Nov 10.
Published in final edited form as: J Am Chem Soc. 2010 Nov 10;132(44):15512–15513. doi: 10.1021/ja107329k

Table 1.

Substrate scope of the reactiona

entry substrate product isolated yield (%)
1 graphic file with name nihms-247031-t0002.jpg graphic file with name nihms-247031-t0003.jpg 80
2 graphic file with name nihms-247031-t0004.jpg graphic file with name nihms-247031-t0005.jpg 88
3b graphic file with name nihms-247031-t0006.jpg graphic file with name nihms-247031-t0007.jpg 93
4 graphic file with name nihms-247031-t0008.jpg graphic file with name nihms-247031-t0009.jpg 93
5 graphic file with name nihms-247031-t0010.jpg graphic file with name nihms-247031-t0011.jpg 76c
6 graphic file with name nihms-247031-t0012.jpg graphic file with name nihms-247031-t0013.jpg 93c
7d graphic file with name nihms-247031-t0014.jpg graphic file with name nihms-247031-t0015.jpg 86c
8 graphic file with name nihms-247031-t0016.jpg graphic file with name nihms-247031-t0017.jpg 79e
9 graphic file with name nihms-247031-t0018.jpg graphic file with name nihms-247031-t0019.jpg 81
a

Reaction conditions: diazoketone and PhCO2Ag (10 mol%) in CH2Cl2 (0.2 M).

b

20 mol% of PhCO2Ag was used.

c

ee was determined by 19F NMR (Mosher ester derivatives); only one isomer was observed.

d

Ag2O (10 mol%) and C2H4Cl2 (0.2 M) were used.

e

dr was determined by 1H NMR; only one isomer was observed.