Table 1. Type (and number) of substrates transformed by toluene 1,2-dioxygenase, EC 1.14.12.11, from Ps.putida F1a.
Monocyclic aromatics (69) |
Dioxygenation (60) |
Monooxygenation (5) |
Sulfoxidation (4) |
Fused aromatics (3) |
Linked aromatics (7) |
Aliphatic olefins (17) |
Allylic methyl group monooxygenation (8) |
Monooxygenation with allylic rearrangement (1) |
Dioxygenation (8) |
Other substrates (12) |
aTaken from a complete list of 108 reactions, J.Liu and A.Negrete (2000) Toluene Dioxygenase Reactions. http://www.labmed.umn.edu/umbbd/tol/tdo.html