| Mn1—O4 | 2.158 (9) | N1—C5 | 1.365 (15) |
| Mn1—O3 | 2.184 (8) | N1—C1 | 1.378 (16) |
| Mn1—O2 | 2.224 (8) | C1—C2 | 1.366 (19) |
| Mn1—O1 | 2.281 (9) | C1—H1 | 0.94 |
| Mn1—Br2 | 2.608 (2) | C2—C3 | 1.40 (2) |
| Mn1—Br1 | 2.699 (2) | C2—H2 | 0.94 |
| O1—C6 | 1.261 (14) | C3—C4 | 1.394 (18) |
| O2—C6i | 1.217 (14) | C3—H3 | 0.94 |
| O3—H3A | 0.83 | C4—C5 | 1.378 (16) |
| O3—H3B | 1.10 | C4—H4 | 0.94 |
| O4—H4A | 0.83 | C5—C6 | 1.529 (18) |
| O4—H4B | 1.02 | C6—O2ii | 1.217 (14) |
| O4—Mn1—O3 | 171.1 (4) | Mn1—O4—H4B | 115 |
| O4—Mn1—O2 | 86.1 (4) | H4A—O4—H4B | 129 |
| O3—Mn1—O2 | 87.1 (3) | C5—N1—C1 | 120.9 (11) |
| O4—Mn1—O1 | 85.2 (4) | C2—C1—N1 | 120.3 (12) |
| O3—Mn1—O1 | 89.3 (3) | C2—C1—H1 | 119.9 |
| O2—Mn1—O1 | 93.0 (3) | N1—C1—H1 | 119.9 |
| O4—Mn1—Br2 | 95.8 (3) | C1—C2—C3 | 119.5 (12) |
| O3—Mn1—Br2 | 90.8 (3) | C1—C2—H2 | 120.3 |
| O2—Mn1—Br2 | 177.4 (3) | C3—C2—H2 | 120.3 |
| O1—Mn1—Br2 | 85.3 (2) | C4—C3—C2 | 119.9 (13) |
| O4—Mn1—Br1 | 92.1 (3) | C4—C3—H3 | 120.1 |
| O3—Mn1—Br1 | 93.7 (2) | C2—C3—H3 | 120.1 |
| O2—Mn1—Br1 | 89.9 (2) | C5—C4—C3 | 119.5 (12) |
| O1—Mn1—Br1 | 175.9 (2) | C5—C4—H4 | 120.3 |
| Br2—Mn1—Br1 | 91.89 (7) | C3—C4—H4 | 120.3 |
| C6—O1—Mn1 | 129.5 (8) | N1—C5—C4 | 120.0 (12) |
| C6i—O2—Mn1 | 136.7 (9) | N1—C5—C6 | 117.1 (10) |
| Mn1—O3—H3A | 110 | C4—C5—C6 | 122.9 (11) |
| Mn1—O3—H3B | 100 | O2ii—C6—O1 | 130.0 (13) |
| H3A—O3—H3B | 134 | O2ii—C6—C5 | 115.9 (11) |
| Mn1—O4—H4A | 109 | O1—C6—C5 | 114.1 (10) |
| O4—Mn1—O1—C6 | −47.0 (11) | C2—C3—C4—C5 | −0.3 (19) |
| O3—Mn1—O1—C6 | 125.9 (11) | C1—N1—C5—C4 | 0.4 (17) |
| O2—Mn1—O1—C6 | 38.8 (11) | C1—N1—C5—C6 | −179.8 (10) |
| Br2—Mn1—O1—C6 | −143.2 (11) | C3—C4—C5—N1 | 1.0 (18) |
| O4—Mn1—O2—C6i | −3.1 (12) | C3—C4—C5—C6 | −178.8 (10) |
| O3—Mn1—O2—C6i | −177.3 (12) | Mn1—O1—C6—O2ii | 107.2 (14) |
| O1—Mn1—O2—C6i | −88.1 (12) | Mn1—O1—C6—C5 | −73.5 (12) |
| Br1—Mn1—O2—C6i | 89.0 (12) | N1—C5—C6—O2ii | −19.0 (15) |
| C5—N1—C1—C2 | −2(2) | C4—C5—C6—O2ii | 160.8 (12) |
| N1—C1—C2—C3 | 3(2) | N1—C5—C6—O1 | 161.6 (10) |
| C1—C2—C3—C4 | −2(2) | C4—C5—C6—O1 | −18.6 (15) |