Cu1—O2 | 1.9012 (18) | C8—C9 | 1.374 (4) |
Cu1—O3 | 1.9071 (18) | C8—H8 | 0.9300 |
Cu1—N1 | 2.020 (2) | C9—C10 | 1.394 (4) |
Cu1—N2 | 2.033 (2) | C9—H9 | 0.9300 |
Cu1—O1W | 2.329 (2) | C10—H10 | 0.9300 |
O1W—H1WA | 0.8500 | C11—C12 | 1.435 (4) |
O1W—H1WB | 0.8500 | C13—C14 | 1.448 (4) |
N1—C1 | 1.328 (3) | C13—H13 | 0.9300 |
N1—C12 | 1.359 (3) | C14—C15 | 1.403 (4) |
N2—C10 | 1.330 (3) | C14—C19 | 1.421 (3) |
N2—C11 | 1.356 (3) | C15—C16 | 1.366 (5) |
O1—C13 | 1.215 (4) | C15—H15 | 0.9300 |
O2—C19 | 1.315 (3) | C16—C17 | 1.379 (4) |
O3—C20 | 1.284 (3) | C16—H16 | 0.9300 |
O4—C20 | 1.231 (3) | C17—C18 | 1.386 (4) |
C1—C2 | 1.403 (4) | C17—H17 | 0.9300 |
C1—H1 | 0.9300 | C18—C19 | 1.426 (4) |
C2—C3 | 1.354 (4) | C18—C20 | 1.502 (3) |
C2—H2 | 0.9300 | C21—N3 | 1.408 (5) |
C3—C4 | 1.420 (4) | C21—H21A | 0.9600 |
C3—H3 | 0.9300 | C21—H21B | 0.9600 |
C4—C12 | 1.395 (3) | C21—H21C | 0.9600 |
C4—C5 | 1.427 (4) | C22—N3 | 1.428 (5) |
C5—C6 | 1.352 (4) | C22—H22A | 0.9600 |
C5—H5 | 0.9300 | C22—H22B | 0.9600 |
C6—C7 | 1.434 (4) | C22—H22C | 0.9600 |
C6—H6 | 0.9300 | N3—C23 | 1.332 (5) |
C7—C11 | 1.400 (3) | C23—O5 | 1.240 (4) |
C7—C8 | 1.401 (4) | C23—H23 | 0.9300 |
O2—Cu1—O3 | 94.58 (8) | C9—C10—H10 | 119.0 |
O2—Cu1—N1 | 172.36 (8) | N2—C11—C7 | 123.8 (2) |
O3—Cu1—N1 | 89.63 (8) | N2—C11—C12 | 116.4 (2) |
O2—Cu1—N2 | 93.28 (8) | C7—C11—C12 | 119.8 (2) |
O3—Cu1—N2 | 166.80 (9) | N1—C12—C4 | 123.4 (2) |
N1—Cu1—N2 | 81.45 (8) | N1—C12—C11 | 116.5 (2) |
O2—Cu1—O1W | 95.02 (8) | C4—C12—C11 | 120.1 (2) |
O3—Cu1—O1W | 96.84 (9) | O1—C13—C14 | 125.5 (3) |
N1—Cu1—O1W | 90.80 (8) | O1—C13—H13 | 117.2 |
N2—Cu1—O1W | 93.03 (8) | C14—C13—H13 | 117.2 |
Cu1—O1W—H1WA | 114.5 | C15—C14—C19 | 120.6 (3) |
Cu1—O1W—H1WB | 115.6 | C15—C14—C13 | 118.5 (2) |
H1WA—O1W—H1WB | 107.7 | C19—C14—C13 | 121.0 (2) |
C1—N1—C12 | 118.3 (2) | C16—C15—C14 | 120.7 (3) |
C1—N1—Cu1 | 128.79 (18) | C16—C15—H15 | 119.6 |
C12—N1—Cu1 | 112.92 (16) | C14—C15—H15 | 119.6 |
C10—N2—C11 | 117.8 (2) | C15—C16—C17 | 119.3 (3) |
C10—N2—Cu1 | 129.47 (18) | C15—C16—H16 | 120.3 |
C11—N2—Cu1 | 112.70 (16) | C17—C16—H16 | 120.3 |
C19—O2—Cu1 | 123.98 (16) | C16—C17—C18 | 122.8 (3) |
C20—O3—Cu1 | 126.98 (17) | C16—C17—H17 | 118.6 |
N1—C1—C2 | 121.9 (3) | C18—C17—H17 | 118.6 |
N1—C1—H1 | 119.1 | C17—C18—C19 | 118.9 (2) |
C2—C1—H1 | 119.1 | C17—C18—C20 | 116.5 (2) |
C3—C2—C1 | 120.3 (3) | C19—C18—C20 | 124.5 (2) |
C3—C2—H2 | 119.8 | O2—C19—C14 | 117.8 (2) |
C1—C2—H2 | 119.8 | O2—C19—C18 | 124.5 (2) |
C2—C3—C4 | 119.2 (2) | C14—C19—C18 | 117.7 (2) |
C2—C3—H3 | 120.4 | O4—C20—O3 | 120.9 (2) |
C4—C3—H3 | 120.4 | O4—C20—C18 | 119.2 (2) |
C12—C4—C3 | 116.9 (2) | O3—C20—C18 | 119.9 (2) |
C12—C4—C5 | 119.1 (2) | N3—C21—H21A | 109.5 |
C3—C4—C5 | 124.0 (2) | N3—C21—H21B | 109.5 |
C6—C5—C4 | 121.1 (2) | H21A—C21—H21B | 109.5 |
C6—C5—H5 | 119.5 | N3—C21—H21C | 109.5 |
C4—C5—H5 | 119.5 | H21A—C21—H21C | 109.5 |
C5—C6—C7 | 121.1 (2) | H21B—C21—H21C | 109.5 |
C5—C6—H6 | 119.4 | N3—C22—H22A | 109.5 |
C7—C6—H6 | 119.4 | N3—C22—H22B | 109.5 |
C11—C7—C8 | 117.1 (2) | H22A—C22—H22B | 109.5 |
C11—C7—C6 | 118.8 (2) | N3—C22—H22C | 109.5 |
C8—C7—C6 | 124.1 (2) | H22A—C22—H22C | 109.5 |
C9—C8—C7 | 119.0 (2) | H22B—C22—H22C | 109.5 |
C9—C8—H8 | 120.5 | C23—N3—C21 | 119.7 (3) |
C7—C8—H8 | 120.5 | C23—N3—C22 | 121.6 (4) |
C8—C9—C10 | 120.3 (3) | C21—N3—C22 | 118.5 (4) |
C8—C9—H9 | 119.9 | O5—C23—N3 | 123.8 (3) |
C10—C9—H9 | 119.9 | O5—C23—H23 | 118.1 |
N2—C10—C9 | 122.1 (2) | N3—C23—H23 | 118.1 |
N2—C10—H10 | 119.0 | ||
O3—Cu1—N1—C1 | −11.6 (2) | C8—C7—C11—N2 | −0.1 (4) |
N2—Cu1—N1—C1 | 178.2 (2) | C6—C7—C11—N2 | 179.4 (2) |
O1W—Cu1—N1—C1 | 85.2 (2) | C8—C7—C11—C12 | −179.5 (2) |
O3—Cu1—N1—C12 | 170.25 (17) | C6—C7—C11—C12 | 0.0 (3) |
N2—Cu1—N1—C12 | 0.02 (16) | C1—N1—C12—C4 | 1.3 (4) |
O1W—Cu1—N1—C12 | −92.91 (17) | Cu1—N1—C12—C4 | 179.64 (18) |
O2—Cu1—N2—C10 | 6.0 (2) | C1—N1—C12—C11 | −178.4 (2) |
O3—Cu1—N2—C10 | 132.5 (3) | Cu1—N1—C12—C11 | 0.0 (3) |
N1—Cu1—N2—C10 | −179.5 (2) | C3—C4—C12—N1 | −0.6 (4) |
O1W—Cu1—N2—C10 | −89.2 (2) | C5—C4—C12—N1 | −179.8 (2) |
O2—Cu1—N2—C11 | −174.44 (16) | C3—C4—C12—C11 | 179.0 (2) |
O3—Cu1—N2—C11 | −48.0 (4) | C5—C4—C12—C11 | −0.1 (4) |
N1—Cu1—N2—C11 | −0.01 (15) | N2—C11—C12—N1 | 0.0 (3) |
O1W—Cu1—N2—C11 | 90.35 (16) | C7—C11—C12—N1 | 179.4 (2) |
O3—Cu1—O2—C19 | 21.4 (2) | N2—C11—C12—C4 | −179.7 (2) |
N2—Cu1—O2—C19 | −169.2 (2) | C7—C11—C12—C4 | −0.3 (3) |
O1W—Cu1—O2—C19 | −75.9 (2) | O1—C13—C14—C15 | 4.5 (5) |
O2—Cu1—O3—C20 | −26.0 (2) | O1—C13—C14—C19 | −175.7 (3) |
N1—Cu1—O3—C20 | 160.4 (2) | C19—C14—C15—C16 | 0.5 (4) |
N2—Cu1—O3—C20 | −152.3 (3) | C13—C14—C15—C16 | −179.7 (3) |
O1W—Cu1—O3—C20 | 69.7 (2) | C14—C15—C16—C17 | −0.9 (5) |
C12—N1—C1—C2 | −1.1 (4) | C15—C16—C17—C18 | 0.8 (5) |
Cu1—N1—C1—C2 | −179.2 (2) | C16—C17—C18—C19 | −0.3 (4) |
N1—C1—C2—C3 | 0.3 (4) | C16—C17—C18—C20 | −178.7 (3) |
C1—C2—C3—C4 | 0.3 (4) | Cu1—O2—C19—C14 | 168.07 (16) |
C2—C3—C4—C12 | −0.2 (4) | Cu1—O2—C19—C18 | −12.3 (3) |
C2—C3—C4—C5 | 178.9 (3) | C15—C14—C19—O2 | 179.7 (2) |
C12—C4—C5—C6 | 0.8 (4) | C13—C14—C19—O2 | −0.1 (4) |
C3—C4—C5—C6 | −178.3 (3) | C15—C14—C19—C18 | 0.1 (4) |
C4—C5—C6—C7 | −1.1 (4) | C13—C14—C19—C18 | −179.7 (2) |
C5—C6—C7—C11 | 0.7 (4) | C17—C18—C19—O2 | −179.8 (2) |
C5—C6—C7—C8 | −179.9 (3) | C20—C18—C19—O2 | −1.5 (4) |
C11—C7—C8—C9 | 0.0 (4) | C17—C18—C19—C14 | −0.2 (3) |
C6—C7—C8—C9 | −179.4 (3) | C20—C18—C19—C14 | 178.1 (2) |
C7—C8—C9—C10 | 0.0 (4) | Cu1—O3—C20—O4 | −162.1 (2) |
C11—N2—C10—C9 | −0.2 (4) | Cu1—O3—C20—C18 | 19.6 (3) |
Cu1—N2—C10—C9 | 179.35 (19) | C17—C18—C20—O4 | −2.0 (4) |
C8—C9—C10—N2 | 0.1 (4) | C19—C18—C20—O4 | 179.7 (2) |
C10—N2—C11—C7 | 0.2 (3) | C17—C18—C20—O3 | 176.3 (2) |
Cu1—N2—C11—C7 | −179.38 (18) | C19—C18—C20—O3 | −2.0 (4) |
C10—N2—C11—C12 | 179.6 (2) | C21—N3—C23—O5 | −0.7 (6) |
Cu1—N2—C11—C12 | 0.0 (3) | C22—N3—C23—O5 | −176.8 (4) |