Table 1.
MH+ | Sequence |
---|---|
961.4 | [IL]a[IL]QESSER |
808.4 | YGA[IL]EQK |
956.6 | AE[IL]TNRPR |
936.52 | KYGA[IL]EQK |
1041.48 | {DF}bEF[IL]ENK |
1370.63 | FADC*S[IL][IL]YPER |
1262.6 | M(O)cAD[IL][IL]GANWQK |
1246.58 | MAD[IL][IL]GANWQK |
1278.6 | MAD[IL][IL]GANW(O2)cQK |
2051.08 | {DT/ESd}VY[IL][IL]G[QK]eE[IL]GGTDTVE[IL]K |
1526.75 | RFADC*S[IL][IL]YPER |
1385.76 | [IL]F[IL]NE[QK]VFTFK |
1669.9 | VAN[IL]F[IL]NE[QK] VFTFK |
C* stands for carbamidomethyl Cys.
aLow-energy CID analysis cannot differentiate between isomeric Ile and Leu residues.
bThe order of the amino acids could not be determined.
cOxidation of methionine and tryptophan are common side-reactions.
dAmino acid combinations corresponding to the mass difference observed.
eGln and Lys are isobaric amino acids with identical nominal masses, but different elemental composition. Since the QSTAR mass spectrometer affords a 50 ppm mass accuracy, in most cases these residues could be identified, however there are exceptions.