| Sn1—C1 | 2.136 (3) | C5—C6 | 1.383 (4) |
| Sn1—N1 | 2.269 (2) | C5—H5 | 0.9300 |
| Sn1—N2 | 2.224 (2) | C6—C7 | 1.473 (4) |
| Sn1—S1 | 2.4814 (7) | C7—C8 | 1.483 (4) |
| Sn1—Cl1 | 2.4960 (7) | C8—H8A | 0.9600 |
| Sn1—Cl2 | 2.4701 (8) | C8—H8B | 0.9600 |
| S1—C9 | 1.753 (3) | C8—H8C | 0.9600 |
| N1—C2 | 1.332 (4) | C10—C15 | 1.479 (5) |
| N1—C6 | 1.348 (3) | C10—C11 | 1.488 (6) |
| N2—C7 | 1.292 (3) | C10—H10 | 0.9800 |
| N2—N3 | 1.350 (3) | C11—C12 | 1.529 (5) |
| N3—C9 | 1.326 (3) | C11—H11A | 0.9700 |
| N4—C9 | 1.330 (4) | C11—H11B | 0.9700 |
| N4—C10 | 1.468 (4) | C12—C13 | 1.450 (5) |
| N4—H4 | 0.861 (10) | C12—H12A | 0.9700 |
| C1—H1A | 0.9600 | C12—H12B | 0.9700 |
| C1—H1B | 0.9600 | C13—C14 | 1.453 (6) |
| C1—H1C | 0.9600 | C13—H13A | 0.9700 |
| C2—C3 | 1.383 (5) | C13—H13B | 0.9700 |
| C2—H2 | 0.9300 | C14—C15 | 1.523 (5) |
| C3—C4 | 1.359 (5) | C14—H14A | 0.9700 |
| C3—H3 | 0.9300 | C14—H14B | 0.9700 |
| C4—C5 | 1.372 (4) | C15—H15A | 0.9700 |
| C4—H4A | 0.9300 | C15—H15B | 0.9700 |
| C1—Sn1—N2 | 171.66 (12) | N2—C7—C8 | 122.8 (2) |
| C1—Sn1—N1 | 99.56 (12) | C6—C7—C8 | 121.1 (2) |
| N2—Sn1—N1 | 72.12 (8) | C7—C8—H8A | 109.5 |
| C1—Sn1—Cl2 | 93.43 (11) | C7—C8—H8B | 109.5 |
| N2—Sn1—Cl2 | 86.65 (6) | H8A—C8—H8B | 109.5 |
| N1—Sn1—Cl2 | 85.57 (6) | C7—C8—H8C | 109.5 |
| C1—Sn1—S1 | 109.56 (11) | H8A—C8—H8C | 109.5 |
| N2—Sn1—S1 | 78.74 (6) | H8B—C8—H8C | 109.5 |
| N1—Sn1—S1 | 150.85 (6) | N3—C9—N4 | 117.1 (3) |
| Cl2—Sn1—S1 | 93.69 (3) | N3—C9—S1 | 127.9 (2) |
| C1—Sn1—Cl1 | 92.01 (11) | N4—C9—S1 | 115.0 (2) |
| N2—Sn1—Cl1 | 86.94 (6) | N4—C10—C15 | 110.0 (3) |
| N1—Sn1—Cl1 | 86.53 (6) | N4—C10—C11 | 110.1 (3) |
| Cl2—Sn1—Cl1 | 171.05 (3) | C15—C10—C11 | 110.8 (3) |
| S1—Sn1—Cl1 | 91.18 (3) | N4—C10—H10 | 108.6 |
| C9—S1—Sn1 | 95.70 (9) | C15—C10—H10 | 108.6 |
| C2—N1—C6 | 120.1 (3) | C11—C10—H10 | 108.6 |
| C2—N1—Sn1 | 124.3 (2) | C10—C11—C12 | 111.5 (3) |
| C6—N1—Sn1 | 115.58 (17) | C10—C11—H11A | 109.3 |
| C7—N2—N3 | 118.5 (2) | C12—C11—H11A | 109.3 |
| C7—N2—Sn1 | 119.51 (17) | C10—C11—H11B | 109.3 |
| N3—N2—Sn1 | 121.94 (16) | C12—C11—H11B | 109.3 |
| C9—N3—N2 | 115.7 (2) | H11A—C11—H11B | 108.0 |
| C9—N4—C10 | 126.0 (3) | C13—C12—C11 | 112.3 (3) |
| C9—N4—H4 | 123 (2) | C13—C12—H12A | 109.1 |
| C10—N4—H4 | 111 (2) | C11—C12—H12A | 109.1 |
| Sn1—C1—H1A | 109.5 | C13—C12—H12B | 109.1 |
| Sn1—C1—H1B | 109.5 | C11—C12—H12B | 109.1 |
| H1A—C1—H1B | 109.5 | H12A—C12—H12B | 107.9 |
| Sn1—C1—H1C | 109.5 | C12—C13—C14 | 113.1 (4) |
| H1A—C1—H1C | 109.5 | C12—C13—H13A | 109.0 |
| H1B—C1—H1C | 109.5 | C14—C13—H13A | 109.0 |
| N1—C2—C3 | 121.5 (3) | C12—C13—H13B | 109.0 |
| N1—C2—H2 | 119.3 | C14—C13—H13B | 109.0 |
| C3—C2—H2 | 119.3 | H13A—C13—H13B | 107.8 |
| C4—C3—C2 | 119.0 (3) | C13—C14—C15 | 113.3 (4) |
| C4—C3—H3 | 120.5 | C13—C14—H14A | 108.9 |
| C2—C3—H3 | 120.5 | C15—C14—H14A | 108.9 |
| C3—C4—C5 | 119.6 (3) | C13—C14—H14B | 108.9 |
| C3—C4—H4A | 120.2 | C15—C14—H14B | 108.9 |
| C5—C4—H4A | 120.2 | H14A—C14—H14B | 107.7 |
| C4—C5—C6 | 119.7 (3) | C10—C15—C14 | 112.7 (4) |
| C4—C5—H5 | 120.1 | C10—C15—H15A | 109.0 |
| C6—C5—H5 | 120.1 | C14—C15—H15A | 109.0 |
| N1—C6—C5 | 120.1 (2) | C10—C15—H15B | 109.0 |
| N1—C6—C7 | 116.6 (2) | C14—C15—H15B | 109.0 |
| C5—C6—C7 | 123.4 (2) | H15A—C15—H15B | 107.8 |
| N2—C7—C6 | 116.1 (2) | ||
| C1—Sn1—S1—C9 | −178.73 (15) | C3—C4—C5—C6 | −1.9 (5) |
| N2—Sn1—S1—C9 | 2.07 (10) | C2—N1—C6—C5 | 1.0 (4) |
| N1—Sn1—S1—C9 | 3.74 (16) | Sn1—N1—C6—C5 | −176.8 (2) |
| Cl2—Sn1—S1—C9 | −83.77 (9) | C2—N1—C6—C7 | 180.0 (2) |
| Cl1—Sn1—S1—C9 | 88.72 (9) | Sn1—N1—C6—C7 | 2.1 (3) |
| C1—Sn1—N1—C2 | 2.9 (3) | C4—C5—C6—N1 | 0.8 (4) |
| N2—Sn1—N1—C2 | −177.8 (2) | C4—C5—C6—C7 | −178.0 (3) |
| Cl2—Sn1—N1—C2 | −89.9 (2) | N3—N2—C7—C6 | −176.5 (2) |
| S1—Sn1—N1—C2 | −179.50 (18) | Sn1—N2—C7—C6 | 4.4 (3) |
| Cl1—Sn1—N1—C2 | 94.3 (2) | N3—N2—C7—C8 | 2.6 (4) |
| C1—Sn1—N1—C6 | −179.4 (2) | Sn1—N2—C7—C8 | −176.5 (2) |
| N2—Sn1—N1—C6 | −0.01 (17) | N1—C6—C7—N2 | −4.3 (3) |
| Cl2—Sn1—N1—C6 | 87.89 (18) | C5—C6—C7—N2 | 174.6 (2) |
| S1—Sn1—N1—C6 | −1.7 (3) | N1—C6—C7—C8 | 176.6 (2) |
| Cl1—Sn1—N1—C6 | −87.92 (18) | C5—C6—C7—C8 | −4.5 (4) |
| C1—Sn1—N2—C7 | 1.9 (9) | N2—N3—C9—N4 | −179.0 (3) |
| N1—Sn1—N2—C7 | −2.46 (18) | N2—N3—C9—S1 | 1.1 (3) |
| Cl2—Sn1—N2—C7 | −88.88 (19) | C10—N4—C9—N3 | 2.6 (5) |
| S1—Sn1—N2—C7 | 176.68 (19) | C10—N4—C9—S1 | −177.5 (3) |
| Cl1—Sn1—N2—C7 | 84.87 (19) | Sn1—S1—C9—N3 | −2.6 (3) |
| C1—Sn1—N2—N3 | −177.3 (8) | Sn1—S1—C9—N4 | 177.5 (2) |
| N1—Sn1—N2—N3 | 178.4 (2) | C9—N4—C10—C15 | −120.0 (5) |
| Cl2—Sn1—N2—N3 | 91.99 (17) | C9—N4—C10—C11 | 117.6 (4) |
| S1—Sn1—N2—N3 | −2.45 (17) | N4—C10—C11—C12 | 175.8 (4) |
| Cl1—Sn1—N2—N3 | −94.26 (17) | C15—C10—C11—C12 | 53.9 (6) |
| C7—N2—N3—C9 | −177.5 (2) | C10—C11—C12—C13 | −54.4 (7) |
| Sn1—N2—N3—C9 | 1.6 (3) | C11—C12—C13—C14 | 52.4 (7) |
| C6—N1—C2—C3 | −1.8 (4) | C12—C13—C14—C15 | −50.4 (8) |
| Sn1—N1—C2—C3 | 175.8 (2) | N4—C10—C15—C14 | −174.0 (5) |
| N1—C2—C3—C4 | 0.7 (5) | C11—C10—C15—C14 | −52.0 (7) |
| C2—C3—C4—C5 | 1.2 (5) | C13—C14—C15—C10 | 50.5 (8) |