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Formal diagrams of the porphinato core displaying perpendicular displacements, in units of 0.01Å, of the core atoms from the 24-atom mean plane. Also entered on the diagrams are the values of the individual bond distances in the inner 16-membered rings. Note the alternating short-long pattern of the N–Ca and Ca–Cm bond distances. [Fe(TEtP.)(Cl)]SbCl6 (top), [Fe(TPrP.)(Cl)]SbCl6 (bottom).
