Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
HOMO-LUMO energy gap and change in dipole moment due to ICT.
| Substrate | ΔE (eV)a | Ep(ox) (V)b | Ep(red) (V)b | ΔE (eV)c |
| 1a | 3.42 | +1.60 | −2.14 | 3.74 |
| 1b | 3.41 | +1.65 | −2.02 | 3.67 |
| 1c | 3.30 | +1.68 | −1.85 | 3.53 |
| 1d | 3.27 | +1.66 | −1.70 | 3.36 |
| 1e | 3.20 | +1.63 | −1.63 | 3.26 |
| 1f | 3.19 | — | — | — |
| 1g | 2.97 | +0.76 | −2.27 | 3.03 |
aHOMO–LUMO energy gap estimated on the basis of absorption data, bat 0.1 Vs−1 scan rate, cHOMO–LUMO energy gap estimated on the basis of electrochemical data.
