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. Author manuscript; available in PMC: 2011 Dec 6.
Published in final edited form as: Inorg Chem. 2010 Nov 3;49(23):10984–10991. doi: 10.1021/ic101469e

Figure 2.

Figure 2

Formal diagrams of the porphyrinato cores. [Fe(TPP)(Hdmpz)] (top) and [Fe(Tp-OCH3PP)(Hdmpz)] (bottom). Illustrated are the displacements of each atom from the mean plane of the four pyrrole nitrogen in units of 0.01 Å. Positive values of displacement are toward the imidazole ligand. The diagrams also show the orientation of the pyrazole ligand with respect to the atoms of the porphyrin core. The location of the methyl group at the α-position of the coordinated nitrogen is represented by the circle.