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. Author manuscript; available in PMC: 2011 Dec 1.
Published in final edited form as: J Am Chem Soc. 2010 Nov 9;132(47):16977–16986. doi: 10.1021/ja107177m

Figure 5.

Figure 5

Reactions of [Co(13-TMC)(O2)]+ (4) with cyclohexanecarboxaldehyde (CCA) in acetonitrile at 25 °C. a) UV-vis spectral changes of 4 (2 mM) upon addition of 40 equiv of CCA. Inset shows the time course of the absorbance at 380 nm. b) Plot of kobs against CCA concentration to determine a second-order rate constant. c) Plot of first-order rate constants against 1/T to determine activation parameters for the reaction of 4 (2 mM) and 30 equiv of CCA.