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. Author manuscript; available in PMC: 2011 Dec 1.
Published in final edited form as: J Am Chem Soc. 2010 Nov 9;132(47):16977–16986. doi: 10.1021/ja107177m

Figure 6.

Figure 6

Spectral evidence for O2-transfer from [Co(12-TMC)(O2)]+ (2) to [Mn(14-TMC)]2+. a) UV-vis spectral changes showing the disappearance of 2 (blue line) and the appearance of [Mn(14-TMC)(O2)]+ (5) (red line) upon addition of [Mn(14-TMC)]2+ (2 mM) to a solution of 2 (2 mM) in CH3CN at 25 °C. b) ESI-MS changes of 2 at m/z 319.1 and 5 at m/z 343.2 in the reaction of 2 (2 mM) and [Mn(14- TMC)]2+ (2 mM) in CH3CN at 25 °C.