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. Author manuscript; available in PMC: 2010 Dec 2.
Published in final edited form as: Chemistry. 2010 Sep 17;16(35):10616–10628. doi: 10.1002/chem.201001018

Figure 2.

Figure 2

Simple model for secondary 2H KIEs resulting from differences in zero-point energy in a vibrational coordinate that is orthogonal to the reaction coordinate.