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. 2010 Jul 12;107(48):20652–20654. doi: 10.1073/pnas.1003597107

Fig. 1.

Fig. 1.

Possible mechanism for the phosphine-catalyzed asymmetric γ-addition of a malonate ester to an activated allene (for the sake of simplicity, only one E/Z isomer of the intermediates is illustrated and all of the elementary steps are drawn as irreversible).