Table 2.
Transfer rate constants, light-harvesting efficiencies and excitation lifetimes of a single core complex modeled with PufX placed at the center of the complex described using the kinetic model with HEOM-fitted and with GF rate constants.
| Theoretical framework | ρ(t) | GF | ||
|---|---|---|---|---|
| Partition schemea | I | II | I | II |
| kLH1→RC (ps−1) | 1/58.6 | 1/58.2 | 1/59.1 | 1/59.8 |
| kRC→LH1 (ps−1) | 1/13.5 | 1/13.0 | 1/8.8 | 1/8.6 |
| kLH1→LH1 (ps−1)b | 1/35.3 | 1/82.5 | ||
| kRC→RC (ps−1)b | 1/30.4 | 1/9178 | ||
| Light-harvesting efficiency η (%) | 93.8 | 93.7 | 92.3 | 92.4 |
| Excitation lifetime τ (ps) | 62.6 | 62.5 | 75.8 | 75.6 |
a
c.f. Figure 3.
b
Applicable to partition scheme II only.