Table 2.

Polymerisation results^a.

Entry	Monomer	Initiator	Time [min]	Conversion [%]	Yield [%]	Mnb [kg/mol]	PDIb
1c	4	M2	300	100	89	654	2.7
2c	4	M31	80	100	72	45.5	1.08
3	4	1	80	100	85	106	1.2
4	4	2	80	100	79	68.5	1.3
5	4	3	1080	3	—	—	—
6d	4	3	1140	75	47	53.1	2.3
7c	5	M2	360	100	87	967	2.3
8c	5	M31	90	100	74	64.7	1.09
9	5	1	80	100	87	65.7	1.2
10	5	2	80	100	77	75.3	1.5
11	5	3	1080	78	44	82.8	8.8
12d	5	3	135	90	67	73.3	2.3
13	6	1	75	95	54	130e	5.2
14	6	2	240	92	60	220e	1.9
15	6	3	2880	58	37	190e	2.8

^aReaction conditions: Monomer:Initiator = 300:1; [monomer] = 0.2 mol/L; solvent: CH₂Cl₂; 20 °C.; ^bdetermined by GPC, solvent THF, relative to polystyrene standards; ^cvalues taken from Ref. [30]; ^dsolvent: toluene, temperature: 80 °C; ^eadditionally a second peak with a M_n of about 1000 g/mol was observed.