Table 3.
Results of the catalytic testing.
| Entry | Substrate | Product | cat | Reaction conditions | Conv. [%] |
| 1 |  |
 |
3 1 |
1 mol %; CH2Cl2; 20 °C; 24 h | 93 >99 |
| 2 |  |
 |
3 1 |
5 mol %; toluene; 80 °C; 5 h | 33 35 |
| 3 |  |
 |
3 1 |
1 mol %; CH2Cl2; 20 °C; 20 h | >99 >99 |
| 4 |  |
 |
3 1 |
5 mol %; toluene; 80 °C; 5 h | 15 41 |
| 5 |
 1:2 |
 |
3 1 |
1 mol %; CH2Cl2; 20 °C; 24 h | A = 30; B = 52 A = 69; B = 9 |
| 6 |
 1:2 |
 |
3 1 |
5 mol %; toluene; 80 °C; 5 h | 0 0 |
| 7 |
 1:3 |
 |
3 1 3 1 |
2.5 mol %; CH2Cl2; 40 °C; 22 h 0.5 mol %; CH2Cl2; 40 °C; 17 h |
>99 >99a 75 81b |
| 8 |  |
 |
3 1 |
2.5 mol %; CH2Cl2; 40 °C; 48 h 2.5 mol %; CH2Cl2; 40 °C; 2 h |
>99 >99 |
a4% homodimer of acrylate; b1% homodimer of acrylate.