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. Author manuscript; available in PMC: 2011 Dec 21.

Published in final edited form as: Acc Chem Res. 2010 Sep 28;43(12):1461–1475. doi: 10.1021/ar100047x

Profile for the reaction of benzylamine with methyl cinnamyl carbonate catalyzed by the species generated in situ from [Ir(COD)Cl]₂L1, and H₂NPr (blue, ), the combination of isolated metallacyclic complex 1 and [Ir(COD)Cl]₂ (red, ), or the original system generated by combining [Ir(COD)Cl]₂ and L1 (black, ●).

Inline graphic — Profile for the reaction of benzylamine with methyl cinnamyl carbonate catalyzed by the species generated in situ from [Ir(COD)Cl]₂L1, and H₂NPr (blue, ), the combination of isolated metallacyclic complex 1 and [Ir(COD)Cl]₂ (red, ), or the original system generated by combining [Ir(COD)Cl]₂ and L1 (black, ●).