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UV-vis spectral changes associated with the decay of reduced iron dinitrosyl species formed by addition of 2 equiv of Na2S2O4 to a mixture of 79 μM ToMOCox and DEANO at 25 °C in 25 mM KPi buffer, pH 7.0. Data show the spectra 2 min after addition of reductant (red) and at various intervals until reaction completion after 80 min (black).
