Table 2. Chemical and toxic data for the simulated pyrethroids.
Parameter (unit) | Bifenthrin | λ-cyhalothrin | Esfenvalerate | Permethrin |
Molecular weight (g/mol) | 422.9 | 449.85 | 419.9 | 391.3 |
Octanol-water partition coefficient (KOW, L/kg) | 2.00E+07 | 7.94E+06 | 1.74E+06 | 1.26E+06 |
Vapor pressure (Pa) | 1.78E−05 | 2.00E−07 | 1.20E−09 | 2.00E−06 |
Henry's law constant (Pa*m3/mol) | 7.74E−05 | 2.00E−02 | 4.90E−04 | 1.89E−01 |
Organic-carbon normalized partition coefficient (L/kg) | 2.37E+05 | 1.57E+05 | 5300 | 1.00E+05 |
Half-life (day) | ||||
in soil | 85 | 25 | 44 | 42 |
in water | 8 | 8 | 30 | 23 |
in sediment | 251 | 12 | 71 | 40 |
Method detection limit (ng/g) | ||||
in Domagalski et al. [29] | 2.2 | 2.4 | 2.1 | 1.0 |
in Ensminger et al. [30] | 0.5 | 2.0 | 1.0 | 2.0 |
10-day LC50 (ng/g) | 5.2 | 4.5 | 15.4 | 108 |
Notes:
[1] LC50 = median lethal concentration for Hyalella azteca in sediment containing 1% organic carbon.