Table 7.
Ka for Cl−b |
Ka for Na +c |
Ka for K +c |
||||
---|---|---|---|---|---|---|
43 | 43 + Na+ | 43 + K+ | 43 | 43 + Cl− | 43 | 43 + Cl− |
35 | 50 | 460 | 5 | 25 | 8 | 340 |
Association constants are the average of all receptor protons which exhibit significant complexation-induced shifts. The initial [43]=10 mM; uncertainty ±15%.
43/Cl− association constant in the presence of 1 molar equiv. of metal tetraphenylborate.
43/M+ association constant in the presence of 1 molar equiv. of tetrabutylammonium chloride.