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. Author manuscript; available in PMC: 2011 Jan 11.
Published in final edited form as: Chem Commun (Camb). 2010 Aug 9;46(36):6640–6650. doi: 10.1039/c0cc01254h

Fig. 9.

Fig. 9

ESI-MS/MS of free (top) and TriplatinNC adducted (bottom) 5′-d(TCTCCCAGCGTGCGCCAT) at 100 and 120 V of collisional energy, respectively. The region of enhanced stability is in red. Fragmentation of the glycosidic bonds is prevalent throughout the free oligonucleotide, while the associated fragment ions, (w82−, w92−, and a9-B shown in red) are absent in the adduct. Additionally, the intensity of a7-B and a8-B is dramatically reduced.