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Domain organization and deduced assembly line biosynthesis of tirandamycin. Modules and subunits in gold denote incorporation of the starter unit, those in blue denote incorporation from methylmalonyl-CoA, those in red denote incorporation from malonyl-CoA, and the one in silver denotes incorporation of glycine. Bonds in black denote inter-subunit linkages and oxidative modifications. The presumed inactive KR of TamAI module 1 is shown in black.
