Table 1.
Structures of heterocyclic intermediates used in dye syntheses. Heterocycles (A) are lepidines (3, 10 and 11); or (B) are indolenines (4, 6, 8 and 12); benzothiazole (5); benzoxazole (7); and quinaldine (9). Intermediates 11 and 12 contain carboxylic acid functional groups.
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Intermediate | Het | X | Y | R |
3 | A | H | --- | C4H8SO3- |
4 | B | H | CMe2 | C4H8SO3- |
5 | B | H | S | C4H8SO3- |
6 | B | SO3K | CMe2 | C4H8SO3- |
7 | B | H | O | C4H8SO3- |
8 | B | SO3K | CMe2 | C2H5 |
9 | B | OMe | CH=CH | C4H8SO3- |
10 | A | OMe | --- | C4H8SO3- |
11 | A | H | --- | C5H10CO2H |
12 | B | SO3K | CMe2 | C5H10CO2H |