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Rate constants for conversion of PLP-Schiff base samples in water to PMP in the dark (k), in 50 mW of 440-nm light (λk) and in the presence of heavy atoms.
| Sample | k, s−1 | λk, s−1 | λk + KI, s−1 |
|---|---|---|---|
| PLP-Asp | 6.4 ± 0.1 × 10−7 | 5.4 ± 0.8 × 10−3 | 1.3 ± 0.1 × 10−4 |
| PLP-Val | 5.7 ± 0.1 × 10 −7 | 1.0 ± 0.2 × 10 −3 | 2.9 ± 0.3 × 10 −4 |
| PLP-AIB | 3.9 ± 0.2 × 10 −7 | 3.7 ± 0.7 × 10 −4 | -- |
