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a) The [Ru(η6-arene)(azpy)I]+ complex (17a) is a catalytically active ruthenium-arene anticancer agent; (b) remarkable influence of the leaving group on cytotoxic activity; c) [Ru(η6-arene)(azpy)I]+ complexes can act as catalysts for the oxidation of the major intracellular reducing agent glutathione to glutathione disulfide with concomitant production of reactive oxygen species. Data from ref 77.
