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Photoactive Pt(IV)-iodido complexes. a) molecular structures of complexes 1-3; b) influence of visible light on CT DNA binding of 2 and cytotoxicity of 2 against a TCCSUP human bladder cell line (data from ref. 23); c) NMR studies showed that photosubstitution precedes photoreduction in the reaction of 2 with 5′-GMP upon irradiation.
