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. Author manuscript; available in PMC: 2011 Jan 27.
Published in final edited form as: Angew Chem Int Ed Engl. 2009;48(20):3648–3652. doi: 10.1002/anie.200900236

Table 2.

graphic file with name nihms176407u3.jpg
entry imine allylic alcohol yield (%)[a] (E:Z)[b] dr[b] product
1 graphic file with name nihms176407t17.jpg
1 		graphic file with name nihms176407t18.jpg
19; X = Cl 		59 – – graphic file with name nihms176407t19.jpg
22; X = Cl
2 1 20; X = Br 61 – – 23; X = Br
3 1 21; X = I 60 – – 24; X = I
4 1 graphic file with name nihms176407t20.jpg
25 		53 ≥ 20:1 ≥ 20:1 graphic file with name nihms176407t21.jpg
26
5 1 graphic file with name nihms176407t22.jpg
27 		56 ≥ 20:1 ≥ 20:1 graphic file with name nihms176407t23.jpg
28
6 graphic file with name nihms176407t24.jpg
29 		graphic file with name nihms176407t25.jpg
30 		53 – ≥ 20:1 graphic file with name nihms176407t26.jpg
31
[a]

Reaction conditions: See supporting information for details.

[b]

No evidence was found for the production of stereoisomeric products.