Table 3.

entry	imine	allylic alcohol	yield (%)[a],[b]	product
1	32	20	53	33
2	34	35	52	36
3	1	37	55	38
4	39	4	67	40
5	41; R1, R2 = Me	4	79	42; R1, R2 = Me
6	43[c]; R1 = H, R2 = TMS	4	69	44; R1 = H, R2 = TMS
7	45	4	83	46
8	1	47	72	48 dr ≥ 20:1; (Z):(E) ≥ 20:1

^[a]Reaction conditions: See supporting information for details.

^[b]No evidence was found for the production of stereoisomeric products.

^[c]Compound 43 was used as a mixture of alkene isomers (E:Z = 4:1).