Table 3.
MWCNT | Gas [gas-phase probe molecules] |
N(CH3)3 [acidic sites] |
HCl [basic sites] |
CF3COOH [basic sites] |
NH2OH [carbonyl functions] |
O3 [oxidisable sites] |
NO2 [oxidisable sites] |
---|---|---|---|---|---|---|---|
NT1 | N°/mga | 3.0 · 1015 | 8.1 · 1016 | 2.4 · 1016 | 2.4 · 1017 | 3.9 · 1018 | 1.2 · 1016 |
N°/cm2b | 1.32 · 1012 | 35.6 · 1012 | 10.6 · 1012 | 105.5 · 1012 | 1715 · 1012 | 5.3 · 1012 | |
NT2 | N°/mga | 6.4 · 1015 | 4.4 · 1016 | 5.9 · 1015 | 3.4 · 1017 | 1.8 · 1017 | 1.2 · 1015 |
N°/cm2b | 11.8 · 1012 | 81.3 · 1012 | 1.1 · 1012 | 628.5 · 1012 | 332.7 · 1012 | 2.2 · 1012 | |
NT3 | N°/mga | 2.6 · 1014 | 1.4 · 1016 | 5.8 · 1014 | 2.0 · 1017 | 1.1 · 1018 | 1.9 · 1015 |
N°/cm2b | 0.8 · 1012 | 41.2 · 1012 | 1.7 · 1012 | 588 · 1012 | 3235 · 1012 | 5.6 · 1012 |
a Number of probe molecules taken up per mg of deposited nanoparticles.
b Number of probe molecules taken up per square cm of MWCNT (no/cm2), using the BET surface as a surface metric.
NT1, uncoated MWCNT; NT2, MWCNT coated with carboxylic polyacid polymer; NT3, MWCNT coated with polystyrene polybutadiene polymethylacrylate polymer.