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. 2011 Jan 21;8:3. doi: 10.1186/1743-8977-8-3

Table 3.

Characterization using a Knudsen flow reactor of the surface functional groups present on the multi-walled carbon nanotubes (MWCNT)

MWCNT Gas
[gas-phase probe molecules]
N(CH3)3
[acidic sites]
HCl
[basic sites]
CF3COOH
[basic sites]
NH2OH
[carbonyl functions]
O3
[oxidisable sites]
NO2
[oxidisable sites]
NT1 N°/mga 3.0 · 1015 8.1 · 1016 2.4 · 1016 2.4 · 1017 3.9 · 1018 1.2 · 1016

N°/cm2b 1.32 · 1012 35.6 · 1012 10.6 · 1012 105.5 · 1012 1715 · 1012 5.3 · 1012

NT2 N°/mga 6.4 · 1015 4.4 · 1016 5.9 · 1015 3.4 · 1017 1.8 · 1017 1.2 · 1015

N°/cm2b 11.8 · 1012 81.3 · 1012 1.1 · 1012 628.5 · 1012 332.7 · 1012 2.2 · 1012

NT3 N°/mga 2.6 · 1014 1.4 · 1016 5.8 · 1014 2.0 · 1017 1.1 · 1018 1.9 · 1015

N°/cm2b 0.8 · 1012 41.2 · 1012 1.7 · 1012 588 · 1012 3235 · 1012 5.6 · 1012

a Number of probe molecules taken up per mg of deposited nanoparticles.

b Number of probe molecules taken up per square cm of MWCNT (no/cm2), using the BET surface as a surface metric.

NT1, uncoated MWCNT; NT2, MWCNT coated with carboxylic polyacid polymer; NT3, MWCNT coated with polystyrene polybutadiene polymethylacrylate polymer.