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. Author manuscript; available in PMC: 2012 Feb 4.
Published in final edited form as: Org Lett. 2010 Dec 22;13(3):540–542. doi: 10.1021/ol102890k

Table 2.

Alkene Scopea

graphic file with name nihms260585t2.jpg

entry alkene product yieldb
1 graphic file with name nihms260585t3.jpg graphic file with name nihms260585t4.jpg 75%
2 graphic file with name nihms260585t5.jpg graphic file with name nihms260585t6.jpg 84%
3 graphic file with name nihms260585t7.jpg graphic file with name nihms260585t8.jpg 53%
4 graphic file with name nihms260585t9.jpg graphic file with name nihms260585t10.jpg 85%
5 graphic file with name nihms260585t11.jpg graphic file with name nihms260585t12.jpg 80%
6 graphic file with name nihms260585t13.jpg graphic file with name nihms260585t14.jpg 98%
7 graphic file with name nihms260585t15.jpg graphic file with name nihms260585t16.jpg 81%
8 graphic file with name nihms260585t17.jpg graphic file with name nihms260585t18.jpg 46%
a

All reactions were performed by heating the oxime (1 equiv), alkene (3 equiv), [Cp*RhCl2]2 (5 mol %), AgSbF6 (20 mol %), Cu(OAc)2 (2.1 equiv), and THF (0.1 M) in a sealed vial for 20 h at 75 °C.

b

Isolated yields after purification by chromatography are reported.