TABLE 8.
The Solvation of Reactants and Complex in the 1:1 Hydrogen-Bonding of 2,2,2-Trifluoroethanol and Propanone
| Log L | ||||||
|---|---|---|---|---|---|---|
| Solvent | Log K | Log Ks/Kg | TFE | Propanone | Reactants | Complex |
| gas phase | 1.72 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| cyclohexane | 1.21 | −0.51 | 1.40 | 1.86 | 3.26 | 2.75 |
| hexane | 0.99 | −0.58 | 1.49 | 1.92 | 3.41 | 2.83 |
| CCl4 | 0.98 | −0.74 | 1.85 | 2.34 | 4.19 | 3.45 |
| benzene | 1.00 | −0.74 | 2.28 | 2.62 | 4.90 | 4.16 |
| chlorobenzene | 0.82 | −0.90 | 2.23 | 2.64 | 4.87 | 3.97 |
| bromobenzene | 0.80 | −0.92 | 2.17 | 2.62 | 4.79 | 3.87 |
| dichloromethane | 0.41 | −1.31 | 2.73 | 3.20 | 5.93 | 4.62 |
| trichloromethane | 0.22 | −1.50 | 2.65 | 3.26 | 5.91 | 4.41 |
| benzonitrile | 0.16 | −1.56 | 3.30 | 2.85 | 6.15 | 4.59 |
| octanol | 0.10 | −1.62 | 3.53 | 2.31 | 5.84 | 4.22 |
| water | −0.19 | −1.91 | 3.50 | 2.95 | 6.45 | 4.54 |