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. Author manuscript; available in PMC: 2012 Jan 7.
Published in final edited form as: J Chromatogr A. 2010 Oct 31;1218(1):64–73. doi: 10.1016/j.chroma.2010.10.096

Table 4.

Case 2: Results for Optimization of Mixture Ca

1tg 1L 1F 1 φ o 1 φ fin 1nc Δ(1t) Δ(1t)/1tg 1 ϖ 2tg β 1n'c 2nc n'c,2D
Method 1 optimization of mixture C1
5 14.4 0.81 0.00 0.36 101 4.5 0.90 0.045 11.58 10.0 10.1 16 164
12 19.1 0.61 0.00 0.31 131 11.1 0.93 0.085 12.18 5.5 23.6 17 401
24 23.5 0.50 0.00 0.26 157 22.6 0.94 0.144 13.44 3.6 43.4 18 796
49 29.1 0.40 0.00 0.20 187 46.9 0.96 0.252 16.16 2.5 73.8 21 1547
Method 2 optimization of mixture C1
5 9.2 1.27 0.00 0.20 94 4.8 0.96 0.051 11.65 8.8 10.7 16 175
12 14.3 0.82 0.00 0.20 127 11.5 0.96 0.091 12.28 5.2 24.2 17 414
24 20.2 0.58 0.00 0.20 156 23.0 0.96 0.148 13.52 3.6 43.8 18 806
49 28.9 0.40 0.00 0.20 187 47.0 0.96 0.252 16.16 2.5 73.8 21 1548
a

The meanings of symbols in Table 4 are the same as those in Table 3.

1

Mixture C has the least retained solute which elutes close to or slightly later than 1to given 1φo=0.0.