Table 4.
1tg | 1L | 1F | 1 φ o | 1 φ fin | 1nc | Δ(1t) | Δ(1t)/1tg | 1 ϖ | 2tg | β | 1n'c | 2nc | n'c,2D |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Method 1 optimization of mixture C1 | |||||||||||||
5 | 14.4 | 0.81 | 0.00 | 0.36 | 101 | 4.5 | 0.90 | 0.045 | 11.58 | 10.0 | 10.1 | 16 | 164 |
12 | 19.1 | 0.61 | 0.00 | 0.31 | 131 | 11.1 | 0.93 | 0.085 | 12.18 | 5.5 | 23.6 | 17 | 401 |
24 | 23.5 | 0.50 | 0.00 | 0.26 | 157 | 22.6 | 0.94 | 0.144 | 13.44 | 3.6 | 43.4 | 18 | 796 |
49 | 29.1 | 0.40 | 0.00 | 0.20 | 187 | 46.9 | 0.96 | 0.252 | 16.16 | 2.5 | 73.8 | 21 | 1547 |
Method 2 optimization of mixture C1 | |||||||||||||
5 | 9.2 | 1.27 | 0.00 | 0.20 | 94 | 4.8 | 0.96 | 0.051 | 11.65 | 8.8 | 10.7 | 16 | 175 |
12 | 14.3 | 0.82 | 0.00 | 0.20 | 127 | 11.5 | 0.96 | 0.091 | 12.28 | 5.2 | 24.2 | 17 | 414 |
24 | 20.2 | 0.58 | 0.00 | 0.20 | 156 | 23.0 | 0.96 | 0.148 | 13.52 | 3.6 | 43.8 | 18 | 806 |
49 | 28.9 | 0.40 | 0.00 | 0.20 | 187 | 47.0 | 0.96 | 0.252 | 16.16 | 2.5 | 73.8 | 21 | 1548 |
The meanings of symbols in Table 4 are the same as those in Table 3.
Mixture C has the least retained solute which elutes close to or slightly later than 1to given 1φo=0.0.