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. Author manuscript; available in PMC: 2012 Jan 7.
Published in final edited form as: J Chromatogr A. 2010 Oct 31;1218(1):64–73. doi: 10.1016/j.chroma.2010.10.096

Table 5.

Case 3: Results for Optimization of Mixture Da

1tg 1L 1F 1 φ o 1 φ fin 1nc Δ(1t) Δ(1t)/1tg 1 ϖ 2tg β 1n'c 2nc n'c,2D
Method 1 optimization of mixture D1
5 9.3 1.26 0.00 0.80 101 4.0 0.80 0.040 11.52 11.3 9.0 16 146
12 14.3 0.82 0.00 0.80 135 9.6 0.80 0.071 11.94 6.5 20.8 17 348
24 20.3 0.58 0.00 0.80 163 19.2 0.80 0.118 12.84 4.2 38.5 18 682
49 25.2 0.46 0.00 0.76 192 40.9 0.83 0.213 15.16 2.8 68.9 20 1381
Method 2 optimization of mixture D1
5 3.0 3.89 0.00 0.50 53 4.9 0.98 0.091 12.29 5.2 10.2 17 175
12 4.8 2.43 0.00 0.51 81 11.6 0.97 0.144 13.44 3.6 22.3 18 408
24 7.9 1.49 0.00 0.55 118 23.0 0.96 0.195 14.70 2.9 40.1 20 786
49 12.7 0.92 0.00 0.58 163 46.5 0.95 0.286 17.02 2.4 69.0 22 1500
a

The meanings of symbols in Table 5 are the same as those in Table 3.

1

Mixture D has the least retained solute which elutes at a time greater than 1to given 1φo=0.0.