Table 1.
Analytical conditions for ATD/GC/MS and HPLC.
| ATD/GC/MS | ||
| ATD | First desorption | 300 °C (10 min) |
| Second desorption | 5 °C → 40 °C/min → 300 °C (10 min) | |
| GC | Column | HP-1 MS (60.0 m × 250 m, 1.00 m) |
| Carrier gas | He | |
| Column temperature | 40 °C (4 min)→7 °C /min →280 °C (10 min) | |
| MS | Analytical mode | SCAN |
| Mass range | m/z = 33–550 | |
| HPLC | ||
| Column | Ascentis RP-Amide (250 mm×4.6 mm, 5 m) | |
| Mobile phase | H2O : CH3CN = 35 : 65 | |
| Flow rate | 1.0 mL/min | |
| Injection volume | 20 L | |
| Column temperature | 35 °C | |
| Detector | Diode Array Detector 360 nm | |