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. Author manuscript; available in PMC: 2012 Mar 1.
Published in final edited form as: Arch Biochem Biophys. 2010 Oct 29;507(1):95–110. doi: 10.1016/j.abb.2010.10.016

Fig. 22.

Fig. 22

A generalized mechanism for Baeyer-Villiger oxidative rearrangement of ketones to esters carried out by cytochrome P450s. The R group is normally bulkier than the R’ group in Baeyer-Villiger oxidations.