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. Author manuscript; available in PMC: 2011 Oct 7.
Published in final edited form as: J Phys Chem B. 2010 Oct 7;114(39):12501–12507. doi: 10.1021/jp105549s

Table 2.

Experimental and viscosity scaled (Table 1) simulation translational diffusion constants for glucose and assorted disaccharides at 25 °C; values at zero concentration, D0, are extrapolated.

c (wt %) c (m) Dsim
(10−6 cm2/s)
Dexp
(10−6 cm2/s)
% error
glucose 0 0 6.80 6.75 a 0.8
8.3 0.50 5.82 5.97 −2.4
15.4 1.01 5.01 5.31 −5.6
26.7 2.02 3.69 4.25 −13.3
35.3 3.03 2.57 3.44 −25.4
42.1 4.04 1.97 2.81 −29.6
47.6 5.05 1.41 2.29 −38.2
trehalose 0 0 5.24 5.08 b 3.1
3.3 0.101 5.12
4.0 0.122 4.67 4.83 c −3.3
9.4 0.303 4.42 3.73 d 18.4
30.2 1.262 2.25 1.41 d 59.6
melibiose 0 0 5.24 4.89 b 7.1
4.9 0.151 4.72
6.5 0.202 4.62
7.9 0.252 4.42
maltose 4.0 0.122 4.94 4.97 c −0.6
a

Ref. 37. Experimental values for concentrations > 0 are interpolated.

b

Ref. 38

c

Ref. 22. These experiment results are in D2O, and are scaled by 1/1.23 to give values for H2O

d

Ref. 39