Table 3.

Reorientational correlation times τ and NMR 1/T₁ of α and β-glucose solutions.

		Sim			Expa
anomer	carbon	τ (ps)	1/T1 (s−1)b	1/T1 (s−1)	Err (%)
	1	10.3	0.624	0.735	−15.1
	2	10.0	0.604	0.709	−14.7
	3	10.0	0.606	0.694	−12.7
α	4	10.0	0.607	0.719	−15.6
	5	10.0	0.605	0.680	−11.0
	6	9.4	1.139	1.190	−4.3
	1	10.5	0.634	0.690	−8.1
	2	10.5	0.636	0.690	−7.9
	3	10.5	0.639	0.725	−11.9
β	4	10.5	0.637	0.735	−13.3
	5	10.5	0.638	0.699	−8.8
	6	9.9	1.202	1.389	−13.5

^a)30 °C, 5 wt% (ca. 0.3 m) in D₂O; ref 23

^b)From τ scaled by data in Table 1 (1.23 × η_exp/η_sim) for D₂O. Statistical errors in the simulated relaxation times are approximately 4%.